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silicotungstic acid : ウィキペディア英語版
silicotungstic acid

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Silicotungstic acid (also known as tungstosilicic acid) is the most commonly encountered heteropoly acid. It is a pale yellow solid with the chemical formula H4(). It is used as a catalyst in the chemical industry.
==Applications==
Silicotungstic acid is used to manufacture ethyl acetate by the alkylation of acetic acid by ethylene:
:C2H4 + CH3CO2H → CH3CO2C2H5
It has also been commercialized for the oxidation of ethylene to acetic acid:〔
:C2H4 + O2 → CH3CO2H
This route is claimed as a "greener" than methanol carbonylation. The heteropoly acid is dispersed on silica gel at 20-30 wt% to maximize catalytic ability.
It has also recently been proposed as a mediator in production of hydrogen through electrolysis of water by a process that would reduce the danger of explosion while allowing efficient hydrogen production at low current densities, conducive to hydrogen production using renewable energy.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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